In database:

600-6500 cm-1

5.6-230 nm

Phosphine (PH₃)
Molecular weight 34 amu
Freezing point -133.5 C
Boiling point -85 C
Dipole moment 0.58 D
HITRAN number 28

Infrared cross-sections from PNNL
FTIR infrared cross-sections from 600 to 6500 cm^-1
Data available at 5 C, 25 C, and 50 C
Spectra is composite of on the order of 10 different pressures,backfilled with nitrogen to 760 T.
Images of PNNL data in cm²/molecule vs. wavenumbers
Images of PNNL data in cm²/molecule vs. microns


Line list from HITRAN 2008
Data from 770 to 3602 cm^-1
Images of HITRAN data on a log scale

Line list from HITRAN 2004
Data from 770 to 2479 cm^-1.
Images of HITRAN 2004 data in cm/molecule vs. wavenumbers
Images of HITRAN 2004 data in cm/molecule vs. microns

Line list from HITRAN 2000
Data from 708 to 1410 cm^-1.
Images of HITRAN 2000 data in cm/molecule vs. wavenumbers

Line list to be submitted to HITRAN
Data from 2724 to 3601 cm^-1.
Images of data in cm^-2atm^-1 vs. wavenumbers

UV cross-sections
Please see The MPI-Mainz UV/VIS Spectral Atlas

Additional References
On the Study of Resonance Interactions and Splittings in the PH₃ Molecule: n₁, n₃, n₂+n₄, and 2n₄ Bands; O.N. Ulenikov et al.; J.Mol.Spec. 215:295-308 (2002).
Figure 1, overview from 1600-9000 cm^-1 (V=n₁+n₃)
Isotopic Effects in XH₃ (C_3v) Molecules: The Lowest Vibrational Bands of PH₂D Reinvestigated; O.N. Ulenikov et al.; J.Mol.Spec. 208:236-248 (2001).
The n₂/n₄ Diad of PH₃; A. Ainetschian et al.; J.Mol.Spec. 181:99-107 (1997).
Phosphine Spectrum at 4-5 mm - Analysis and Line-by-Line Simulation of 2n₂ Band, n₂+n₄ Band, 2n₄ Band, n₁ Band, and n₃ Band; G. Tarrago et al.; J.Mol.Spec. 154:30-42 (1992).

Notes

n₁ 2321 cm^-1 (a₁) stretch
n₂ 992 cm^-1 (a₁) deform
n₃ 2327 cm^-1 (e) stretch
n₄ 1118 cm^-1 (e) deform



List of available data for all molecules in database
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