In database:
600-6500 cm-1
6.2-248 nm
Dimethyl ether ((CH3)2O)
Molecular weight 46.0688 amu
Freezing point -141 C
Boiling point 24.5 C

Infrared cross-sections from PNNL
FTIR infrared cross-sections from 600 to 6500 cm-1
Data available at 5 C, 25 C, and 50 C
Spectra is composite of on the order of 10 different pressures,backfilled with nitrogen to 760 T.
Images of PNNL data in cm2/molecule vs. wavenumbers
Images of PNNL data in cm2/molecule vs. microns

UV cross-sections
Please see The MPI-Mainz UV/VIS Spectral Atlas

Additional references
High-Resolution Analysis of the n6, n17, and n21 Bands of Dimethyl Ether; L.H. Coudert, P. Carcabal, M. Chevalier, M. Broquier, M. Hepp, and M. Herman; J.Mol.Spec. 212:203-207 (2002).
Figures 2 and 3 showing 934-944 and 1105-1115 cm-1.

Notes ch3och3
Fundamental frequencies from NIST Chemistry Webbook / Coudert et al.
(b1 and b2 switched between 2 references.)
n1 2996 cm-1 (a1) CH3 d-stretch / 2993 cm-1 (a1) CH sym-stretch
n2 2817 cm-1 (a1) CH3 s-stretch / 2822 cm-1 (a1) CH2 sym-stretch
n3 1464 cm-1 (a1) CH3 d-deform / 1470 cm-1 (a1) HCH2 sym-bend
n4 1452 cm-1 (a1) CH3 s-deform / 1454 cm-1 (a1) HCH sym-bend
n5 1244 cm-1 (a1) CH3 rock / 1250 cm-1 (a1) CH3 rock
n6 928 cm-1 (a1) CO s-stretch / 933.906 cm-1 (a1) CO sym-stretch
n7 418 cm-1 (a1) COC deform / 424 cm-1 (a1) COC bend
n8 2952 cm-1 (a2) CH3 d-stretch / 2893 cm-1 (a2) CH2 asym-stretch
n9 1464 cm-1 (a2) CH3 d-deform / 1444 cm-1 (a2) HCH asym-bend
n10 1150 cm-1 (a2) CH3 rock / 1150 cm-1 (a2) CH3 rock
n11 203 cm-1 (a2) torsion / 198 cm-1 (a2) torsion
n12 2996 cm-1 (b1) CH3 d-stretch / 2989 cm-1 (b1) CH2 asym-stretch
n13 2817 cm-1 (b1) CH3 s-stretch / 1462 cm-1 (b1) HCH sym-bend
n14 1464 cm-1 (b1) CH3 d-deform / 1181 cm-1 (b1) CH3 rock
n15 1452 cm-1 (b1) CH3 s-deform / 242 cm-1 (b1) torsion
n16 1227 cm-1 (b1) CH3 rock / 2991 cm-1 (b2) CH asym-stretch
n17 1102 cm-1 (b1) CO a-stretch / 2817.385 cm-1 (b2) CH2 sym-stretch
n18 2925 cm-1 (b2) CH3 d-stretch / 1456 cm-1 (b2) HCH asym-bend
n19 1464 cm-1 (b2) CH3 d-deform / 1449 cm-1 (b2) HCH asym-bend
n20 1179 cm-1 (b2) CH3 rock / 1165 cm-1 (b2) CH3 rock
n21 242 cm-1 (b2) torsion / 1103.951 cm-1 (b2) CO asym-stretch



List of available data for all molecules in database
Return to front page